It's because you're using optical. It only has enough bandwidth for core 5.1 compressed (AC3 or DTS) or stereo uncompressed (PCM). mpv is decoding it because it can't be passed through, and it's downmixed to stereo because that's all that can fit in the optical cable. So no EAC3, DTS-HD or TrueHD. mpv can re-encode those to 5.1 AC3, which will work.  Use the audio config I posted above, and unzip the attached zip file to: C:\users\USERNAME\AppData\Roaming mpv.zip
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